Acyl Group

 

 

 

The residual structure after the hydroxyl group has been removed from the carboxyl group of acids, i.e.


Alcohols

 

Compounds of the general formula R – OH when one or more hydroxyl groups replace hydrogen atoms of alkanes.


Aldehydes

 

Carbonyl compounds of the general formula,


 

Alkaeoids

 

Complex nitrogen-containing compounds, principally of plant origin, that posses marked physological properties.


Alkanes [Paraffins]

 

Hydrocarbons of the general formula CaH2n + 2 with each carbon bonded to a maximum of hydrogen atoms.


Alkanes [Olefins]

 

Unsaturated hydrocarbons with one or more pairs of carbon atoms joined by double bonds – one a sigma (s), the other a pi (p) bond.


Alkyl Groups

 

Hydrocarbon groups of the general formula CaH2n + 2 containing one less hydrogen than the parent alkane.


Alkynes [Acetylenes]

 

Unsaturated hydrocarbons with one or more pairs of carbon atoms joined by triple bonds – one a sigma (s), the other two  pi (p) bonds.


Amides

 

Compounds that may be regarded as acyl derivatives of ammoni, e.g.

 

Amines

 

An important class of organic bases that may be regarded as hydrocarbon substitution produces of ammonia,

e.g., R – NH2 – R2N – H, R3N.


Arenes [Aromatic Hydrocarbons]

 

Cyclic hydrocarbons with one or more benzene rings in their structures.


Aryl Group

 

An aromatic hydrocarbon group that contains one less hydrogen than the parent arene, e.g. phenyl, C6H5 .


Atomic Orbital

 

The regions in the space about the nucleus of an atom where an electron is most likely to be found.


Carbohydrates

 

Polyhydroxyl aldehydes or polyhydroxyl ketones, or substances that can be hydrolyzed to such aldehydes or ketones.


Carbonyl Group

 

The reactive group to be found in aldehydes, ketones, and acyl compounds, i.e., C = O


Carboxyl Group

 

The functional group characteristic of the carbonxyl acids,

i.e., 

 

 

CHIRALITY

 

The left-handed or right-handed property possed by compounds that makes possible the existence of enantiomers.


Codon

 

Coding units for specific amino acids made up of triplet combinations of nucleotides in DNA.


Configuration

 

The spartial arrangement of atoms in a molecule that may be changed only by breaking and rearrangine bonds.


Conformations

 

A spatial arrangment of groups in a molecule permitted by their rotation about single bonds.


Conjugated System

 

A system of alternate sing and double bonds through which chemical activity may be transmitted from one part of the molecualr structure to the other.


Covalence

 

Bonding through electron-pair sharing.

Dextrorotatory

 

A term applied to optically active compounds that rotate plane polarized light clockwise or to the right.


Disteroismers

 

Stereoisomers tha are not mirror images of each other.


Electrophilic

Reagent

 

A reagent tha seeks an unshared pair of electrons, i.e. an acid.


Enantiomers

 

Optical isomers tha tare non-superimposable mirror images.


Esters

 

A general class of acid derivaties in which the ionizable hydrogen of the acid has been replaced by a hydrocarbon group.


Ethers

 

A general class of compounds in which two hydrocarbon groups are joined through an oxygen atom.


Fats

 

Solid or semisolid naturally occurring long chain carboxylic acid esters or glycerol.


Free Radical

 

A highly reactive short lived atoms or goup that has an odd, unpaired electron.


Functional Group

 

A structure feature that identifies a family of compounds and bestown upon its members a common property.


Glycols

 

Compounds that contain two hydroxyl groups on adjacent carbon atoms.


Hemacetal

 

An unstable compound formed by the addition of an alcohol to the carboxyl group of an aldehyde.


Heterocyclic

 

A ring compound that contains, in addition to carbon, one or more other kins of atoms.


Hybridized Orbitals

 

Orbitals formed by blending orbitals in different subshells.


 

Hydrocarbons

 

Compounds (mostly obtained from petroleum) that contain only hydrogen and carbon.


Invert Sugar

 

A temporary mixture of equal parts of glucose and fructose formed by hydrolyzing dextrorotatory sucrose.


Isomers

 

Compounds with the same molecular formula but with different structural formulas.

Ketones

 

Carbonyl compounds of the general formula R2C = O.


Levorotatory

 

A term applied to optically active compounds that rotate plane poloraized light counterclockwise or to the left.


Molecular Orbital

 

An orbit formed by the overlap of two atomic orbitals which encompasses more than one nucleus.


Mutarotation

 

A change with time in the rotation of a solution of an optically active compound.


Nucleic Acids

 

High molecular weight natural polymers found in the nuclei and cytoplasms of all living cells.


Nucleophilic Reagent

 

A reagent with an unshared pair of electrons to donate, e.g., a base.


Nucleoside

 

Ribose or deoxyribose substituted at carbon N-glycosidic link by one of five heterocyclic bases.


Nucleotide

 

Phosphoric acid esters of nucleosides, the structural units in both RNA and DNA.


Peptides

 

Chain structures that result when ammino acids condense to form one or more amide linkages.


Phenols

 

Compounds that have one or more hydroxyl groups attached to an aromatic ring.


Polymers

 

Huge molecules formed through the repeated addition or condensation of many simple molecules.


Proteins

 

Complex, high molecular weight polyamides synthesized by living organisms.


Pyrolysis

 

A high temperature decompostion or cracking in which bonds are ruptured to form free radicals.


Racemates

 

Optically inactive mixtures of equal amounts of enantiomers.


Resins

 

Complex noncrystalline, solid or semisolic mixtures of organic compounds either synthetic or or natural origin.


Resonance

 

Term used when two or more electronic formulas can be written for a compound, ion, or radical; actural structure is a hybird of all contributing structures.


Saponification

 

A hydrolysis reaction carried out in an alkaline solution.  The preparation of soaps from fats.


 


Stereoisomerism

 

Isomerism made possible by a variation in the spatial arrangement or atoms or groups in a molecule.


Steric Hindrance

 

A restriction on the reactivity of a group due to the spatical arrangements of neighboring groups.


Steroids [Sterols]

 

A class of cyclopentanophenanthrene derivatives of biological importance, e.g., bile acids, sex hormones.


Terpenes

 

Highly unsaturated naturally occurring compounds in which the structural is isoprene.


Vitamins

 

Naturally occurring compounds, small amounts of which are required in the diet.


 


 














Sugars that have different configurations about one or more chiral centers are called diasteriomers.  If the pair is different in configuration around only one of the chiral centers, then the molecules belong to a subclass of diasteriomers called epimers.

 

One important pair of epimers is glucose and galactose, which differ in configuration at carbon 4.

 
 

 


 

˙  Enantiomers

˙  Rings

˙  Derivatives

 

 

 

˙   Epimer

˙  Mutarotation

 

 

 

 

Carbohydrates

Monosaccharides

Topics

Testing

Options

 


Five carbon rings are called turans, and six carbon rings are pyrans.  The sugars containing these rings are turanoses and pyranoses.

 

The formation of the hemiacetal or hemiketal bond generates a new chiral center because the hydroxyl (-OH) can project above or below the plane of the ring.  This means that a ring can have two different forms, called anomers.  If the hydroxyl points below, it is called an a-anomer.  If it points above, the anomer is b.  The ring itself is not planar, it puckers into what is called a chair conformation.

 
 

 

 

 

 

 

 

 

 

 

 


˙  Forward

 

 

˙  Reverse

 

 

 

˙  Enantiomers

˙  Rings

˙  Derivatives

 

 

 

˙   Epimer

˙  Mutarotation

 

 

 

 

Carbohydrates

Monosaccharides

Topics

Testing

Options

 


The term “ligand” refers to a molecule that physically interacts with a protein, no matter what the reason for the interaction. This is true whether the protein is transporting the ligand, as hemoglobin does when it carries oxygen, or when the protein performs a chemical reaction on the ligand, as an enzyme does.

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

˙  Simple Binding

 

 

˙  Allosteric Binding

 

 

 

Proteins

Ligand Binding

Topics

Testing

Options

 


RESEARCH PAPER IN CHEMISTRY

 

 

 

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5

1.  Topic

 

 

 

1.  Main Points

 

 

 

2.  Scientific Content

 

 

 

2.  Attire/Personality

 

 

 

3.  Extent of Research

 

 

 

3.  Eye Contact/Attention                   Getting

 

 

 

4.  Significance

 

 

 

4.  Transmission

 

 

 

5.  Comparisons

 

 

 

5.  Participation

 

 

 

6.  Advantages/Disadvantages

 

 

 

6.  Closing

 

 

 

7.  Paper: Achievement of Goals

 

 

 

7.  Questions

 

 

 

8.  Consistency of Style

 

 

 

8.  Audio/Visual

 

 

 

9.  Clarity

 

 

 

 

 

 

 

10. Appearance

 

 

 

 

 

 

 

11. Reference/Bibliography

 

 

 

 

 

 

 

12. Meeting Deadlines